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Zinc(II) Complex of Meso-Tetraphenylporphyrin With 4-Methoxyaniline: Crystal Structure and Antimicrobial Activities of 4-Methoxyaniline-5, 10, 15, 20-Tetraphenyl-Porphyrinatozinc (II)

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Date

2014-11-04

Journal Title

Journal ISSN

Volume Title

Publisher

Taylor and Francis Group

Abstract

4-Methoxyaniline-5,10,15,20-tetraphenylporphyrinatozinc(II), [(ZnTPP(MOAN)] 1 was synthesized (MOAN D 4-methoxyaniline) and characterized by elemental analysis and spectroscopic techniques. The molecular structure of 1 was determined by single-crystal X-ray crystallography. The structure revealed a triclinic crystal system and the space group P1 with the central metal adopting slightly distorted square pyramidal geometry with 4-methoxyaniline in the axial position. The antimicrobial activities were carried out using a well diffusion method and the zone of inhibition of four bacteria and two fungi was measured.

Description

Staff Publication

Keywords

Porphyrin,, 4-methoxyaniline,, crystal structure, ,, spectra,, antimicrobial activity

Citation

Obaleye, J. A., Tella, A. C., Obiyenwa, G. K., Simon, N., & Olawale, M. D. (2015). Zinc(II) Complex ofMeso-Tetraphenylporphyrin With 4-Methoxyaniline: Crystal Structure and Antimicrobial Activities of 4-Methoxyaniline-5, 10, 15, 20-Tetraphenyl-Porphyrinatozinc (II). Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 46(4), 589–595. doi:10.1080/15533174.2014.988813