ITACONIC ACID BASED COORDINATION POLYMER: MECHANOCHEMICAL SYNTHESIS, CHARACTERIZATION AND VAPOCHROMIC STUDY

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dc.contributor.authorOlawale, Margaret D.
dc.contributor.authorObaleye, Joshua A.
dc.contributor.authorOladele, Ebenezer O.
dc.date.accessioned2021-03-01T12:23:55Z
dc.date.available2021-03-01T12:23:55Z
dc.date.issued2020-05-30
dc.descriptionStaff Publicationen_US
dc.description.abstractItaconic acid based coordination polymer (CP) was synthesized through a mechanochemical reaction between itaconic acid ligand and copper (II) salt. The [Cu(Itac)2] CP was characterized by elemental analysis, Infrared spectroscopy, UV-Visible spectrophotometry and powder x-ray diffractometric analysis which confirmed its synthesis. In the application of [Cu(Itac)2], vapochromic behavior was carried out with different solvents vapour. Result revealed methanol having the highest sorption values of 1.44 moles. Also, the adsorption of the solvents vapour on [Cu(Itac)2] increased in the order of methanol > DMF > ethanol > acetone > isopropanol > benzene > toluene. The polarity of the solvents, solvent sizes and the unique affinity of [Cu(Itac)2] CP to some solvents may account for trend observed in rate of solvents uptake. These results indicate that [Cu(Itac)2] could be used to remove unwanted solvent vapour from contaminated air due to their reasonably large surface area.en_US
dc.identifier.issn2682-6054
dc.identifier.urihttp://repository.elizadeuniversity.edu.ng/handle/20.500.12398/887
dc.language.isoenen_US
dc.publisherNigerian Research Journal of Chemical Sciencesen_US
dc.subjectCoordination polymer,en_US
dc.subjectItaconic acid, IR, UV-Visible, vapochromicen_US
dc.subjectItaconic acid,en_US
dc.subjectIR,en_US
dc.subjectUV-Visible,en_US
dc.subjectvapochromicen_US
dc.titleITACONIC ACID BASED COORDINATION POLYMER: MECHANOCHEMICAL SYNTHESIS, CHARACTERIZATION AND VAPOCHROMIC STUDYen_US
dc.typeArticleen_US
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